Prime Minister and also in-charge of the Ministries/ Departments not specifically allocated to the charge of any Minister viz.:
| (i) | Ministry of Personnel, Public Grievances & Pensions; |
| (ii) | Ministry of Planning; |
| (iii) | Ministry of Railways; |
| (iv) | Department of Atomic Energy;and |
| (v) | Department of Space |
| CABINET MINISTERS | |
| Shri Pranab Mukherjee Minister of Finance | |
| Shri Sharad Pawar Minister of Agriculture Minister of Food Processing Industries | |
| Shri A. K. Antony Minister of Defence | |
| Shri P. Chidambaram Minister of Home Affairs | |
| Shri S. M. Krishna Minister of External Affairs | |
| Shri Virbhadra Singh Minister of Micro, Small and Medium Enterprises | |
| Shri Vilasrao Deshmukh Minister of Rural Development Minister of Panchayati Raj | |
| Shri Ghulam Nabi Azad Minister of Health and Family Welfare | |
| Shri Sushil Kumar Shinde Minister of Power | |
| Shri M. Veerappa Moily Minister of Law and Justice | |
| Dr. Farooq Abdullah Minister of New and Renewable Energy | |
| Shri S. Jaipal Reddy Minister of Petroleum and Natural Gas | |
| Shri Kamal Nath Minister of Urban Development | |
| Shri Vayalar Ravi Minister of Overseas Indian Affairs Minister of Civil Aviation | |
| Shri Dayanidhi Maran Minister of Textiles | |
| Shri Murli Deora Minister of Corporate Affairs | |
| Smt. Ambika Soni Minister of Information and Broadcasting | |
| Shri Mallikarjun Kharge Minister of Labour and Employment | |
| Shri Kapil Sibal Minister of Human Resource Development Minister of Communications and Information Technology | |
| Shri B. K. Handique Minister of Development of North Eastern Region | |
| Shri Anand Sharma Minister of Commerce and Industry | |
| Shri C. P. Joshi Minister of Road Transport and Highways | |
| Kumari Selja Minister of Housing and Urban Poverty Alleviation Minister of Culture | |
| Shri Subodh Kant Sahay Minister of Tourism | |
| Dr. M. S. Gill Minister of Statistics and Programme Implementation | |
| Shri G. K. Vasan Minister of Shipping | |
| Shri Pawan K. Bansal Minister of Parliamentary Affairs Minister of Science and Technology Minister of Earth Sciences | |
| Shri Mukul Wasnik Minister of Social Justice and Empowerment | |
| Shri Kantilal Bhuria Minister of Tribal Affairs | |
| Shri M. K. Alagiri Minister of Chemicals and Fertilizers | |
| Shri Praful Patel Minister of Heavy Industries and Public Enterprises | |
| Shri Shriprakash Jaiswal Minister of Coal | |
| Shri Salman Khursheed Minister of Water Resources Minister of Minority Affairs | |
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